Photoresist Processing Trouble-Shooting Etchants and Solvents
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Sales Volumes and Qualities
Acetone removes organic impurities from substrates and is well-suited for greasy/oily contaminations. Its high evaporation rate, however, requires a subsequent cleaning step in e. g. isopropyl alcohol in order to avoid striations on the substrate. Acetone is not well-suited as lift-off medium due to the high fire danger when heated and the trend of particles to be lifted to resorb onto the substrate.
Specification of acetone

Isopropyl alcohol is well-suited for rinsing contaminated acetone off as well as removing particles from surfaces. Therefore, this solvent is often used in the second substrate cleaning step after acetone. Additionally, isopropyl alcohol is used as additive for anisotropic Si-etching.
Specification of isopropyl alcohol

Butyl acetate is – besides PGMEA – a suited thinner for AZ® and TI photoresists due to its high boiling point.
Specification of butyl acetate

Ethyl lactate is – besides PGMEA – a suited thinner for AZ® and TI photoresists due to its high boiling point.
Specification of ethyl lactate

Methanol can be used as a powerful solvent for contaminated acetone in a three-step (substrate) cleaning process (acetone ... methanol ... isopropyl alcohol). However, due to its toxicity, its application should be carefully considered.
Specification of methanol

MEK (ethyl methyl ketone) with its low boiling point can be used as additional thinner for spray coating resists, which require a fast resist film drying on the substrate.
Specification of MEK

NMP (1-methyl-2-pyrrolidone) is a powerful lift-off medium due to its physical properties: NMP yields a low vapour pressure (no striation formation), strongly solves organic impurities as well as resists, keeps solved particles in solution, and can be heated due to its high boiling point. For the same reasons, NMP (pure or diluted in H2O) gives a very well-suited stripper for photoresists processed under harsh conditions.
Specification of NMP

PGMEA (1-methoxy-2-propyl-acetate) is the solvent/thinner of almost all AZ® and TI photoresists due to its low vapour pressure and its suppression of particle formation in the (further diluted) resist. Additionally, PGMEA is often used for edge bead removal, since its low vapor pressure prevents further thinning of the coated resist film. The trade name of PGMEA is AZ® EBR Solvent.
Specification of PGMEA

Beside Butyl acetate and ethanol, we supply all solvents listed above in VLSI quality in 2.5 L sales units. Acetone, isopropyl alcohol, and NMP are additionally available in ULSI grade. Other sales units or purification grades on request!
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MicroChemicals® - All you need for microstructuring with short lead times also in small sales volumes:

Photoresists (positive, negative, image reversal, thin and thick resists, spray resists, protective coating ...)
Ancillaries ( developers, thinner, adhesion promoter such as HMDS, remover)
Etchants (acids and the ready-to-use etching mixtures aluminium etch, chromium etch, gold etch und silicon etch)
Solvents (acetone, isopropyl alcohol, MEK ... in VLSI and ULSI quality)